3-Aminophenylboronic acid hydrate

3-Aminophenylboronic acid hydrate - Names and Identifiers

Name	3-aminophenylboronic acid monohydrate
Synonyms	M-APBA TIMTEC-BB SBB004197 boronic acid monohydrate M-AMINOPHENYLBORONIC ACID (3-aminophenyl)boronic acid 3-Aminophenylboronic acid hydrate (3-aminophenyl)boronic acid hydrate 3-aminophenylboronic acid monohydrate M-AMINOPHENYLBORONIC ACID monohydrate 3-Aminobenzeneboronic acid monohydrate Boronic acid, (3-aminophenyl)-, monohydrate (9CI)
CAS	206658-89-1
EINECS	628-553-9
InChI	InChI=1/C6H8BNO2.H2O/c8-6-3-1-2-5(4-6)7(9)10;/h1-4,9-10H,8H2;1H2
InChIKey	XAEOVQODHLLNKX-UHFFFAOYSA-N

3-Aminophenylboronic acid hydrate - Physico-chemical Properties

Molecular Formula	C6H10BNO3
Molar Mass	154.96
Melting Point	94 °C
Boling Point	473°C at 760 mmHg
Flash Point	239.9°C
Solubility	Soluble in DMSO and methanol.
Vapor Presure	9.39E-10mmHg at 25°C
Appearance	Light brown to brown crystals
Color	Beige to brown
BRN	2936342
Storage Condition	Keep in dark place,Sealed in dry,Room Temperature
Sensitive	Hygroscopic
MDL	MFCD00149554

3-Aminophenylboronic acid hydrate - Risk and Safety

Risk Codes	R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection
WGK Germany	3
FLUKA BRAND F CODES	3-10
HS Code	29310095
Hazard Note	Irritant/Hygroscopic
Hazard Class	IRRITANT, HYGROSCOPI

3-Aminophenylboronic acid hydrate - Introduction

3-aminophenylboronic acid monohydrate, chemical formula C6H5B(OH)2NH2 · H2O, also known as APB monohydrate. The following is a description of its nature, use, preparation and safety information:

Nature:
1. Appearance: APB monohydrate is white crystalline powder.
2. Thermal stability: APB monohydrate is stable below 150°C, but it will decompose when it exceeds this temperature.
3. Solubility: APB monohydrate is soluble in water and alcohol solvents, such as ethanol and propanol.

Use:
1. Catalyst: APB monohydrate is widely used in rhenium catalyst systems in organic synthesis, such as oxychlorination agents, proton catalysts and Friedel-Crafts reaction reagents.
2. Additives: APB monohydrate can also be used as a fluorescent dye, polymer stabilizer and Aurora Borealis luminous agent and other additives.

Method:
The preparation method of APB monohydrate is as follows:
1. Phenylboronic acid (C6H5BO2) and aminophenol (C6H6ONH2) reaction in an appropriate solvent, commonly used solvents are water or ethanol.
2. During the reaction, slowly add acid or alkali to adjust the pH value of the reaction solution to keep it within the appropriate range.
3. After completion of the reaction, the solvent was evaporated to obtain white crystals of APB monohydrate.

Safety Information:
1. APB monohydrate is a general chemical, and corresponding laboratory operating procedures and personal protective measures shall be observed.
2. Avoid contact with skin and eyes, such as contact should be immediately washed with plenty of water.
3. Avoid inhaling dust or vapor during use to prevent inhalation from damaging the respiratory system.
4. Storage should be sealed in a dry, cool place, away from the fire and oxidant.

Last Update：2024-04-10 22:29:15